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N-boryl pyridyl anion chemistry
Mechanistic study
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2004
Chiral Ligands for Palladium-Catalyzed Coordination-Assisted Enantioselective C(sp
3
)-H Functionalization Reactions A (Invited Review).
手性配体在钯催化配位辅助对映选择性C(sp
3
)-H键官能团化反应中的应用(中文综述)
Chen-Hui Yuan
,
Lei Jiao*
November 2024
Chin. J. Org. Chem.
2024
, doi: 10.6023/cjoc202406002.
Dual Ligand Enabled Pd-Catalyzed
Ortho
-Alkylation of Iodoarenes.
Xiao-Xia Wang
,
Lei Jiao*
September 2024
J. Am. Chem. Soc.
2024
,
146
, 25552-25561.
Overestimated Halogen Atom Transfer Reactivity of α-Aminoalkyl Radicals.
Weiqun Suo
,
Jian-Qing Qi
,
Songtao Sun
,
Lei Jiao*
,
Xingwei Guo*
September 2024
J. Am. Chem. Soc.
2024
,
146
, 25860-25869.
Thio-Cycloolefin Ligand Enabled Distal Methylation in the Catellani-Type Reaction via a Six-Membered Palladacycle.
Feng-Yuan Wang
,
Yi-Fan Tan
,
Lei Jiao*
June 2024
ChemRxiv
2024
, doi:10.26434/chemrxiv-2024-xn57p.
4-Pyridyl Perfluoroalkyl Sulfide as a Practical Nucleophilic Perfluoroalkylation Reagent.
Fei-Yu Zhou
,
Jun-Yan Chen
,
Lei Jiao*
May 2024
Chem
2024
,
10
, 2311-2323.
Unveiling the Mechanistic Role of Chiral Palladacycles in Pd(II)-Catalyzed Enantioselective C(sp
3
)-H Functionalization.
Chen-Hui Yuan
,
Xiao-Xia Wang
,
Keyun Huang
,
Lei Jiao*
May 2024
Angew. Chem. Int. Ed.
2024
,
63
, e202405062.
Characterization and Monitoring of Transient Enamine Radical Intermediates in Photoredox/Chiral Primary Amine Synergistic Catalytic Cycle.
Shixue Zhang
,
Liang Cheng
,
Jian-Qing Qi
,
Zongbin Jia
,
Long Zhang
,
Lei Jiao*
,
Xingwei Guo*
,
Sanzhong Luo*
April 2024
CCS Chem.
2024
,
6
, 2420-2426.
Direct Observation of All Open-Shell Intermediates in a Photocatalytic Cycle.
Jian-Qing Qi
,
Weiqun Suo
,
Jing Liu
,
Songtao Sun
,
Lei Jiao*
,
Xingwei Guo*
March 2024
J. Am. Chem. Soc.
2024
,
146
, 7140-7145.
Photoinduced Radical Borylation of Alkyl Chlorides.
Lutao Bai
,
Lei Jiao*
February 2024
Eur. J. Org. Chem.
2024
, e202400043.
Thio-Cyclopentene Ligands for Catellani-Type Reactions.
Feng-Yuan Wang
,
Lei Jiao*
January 2024
Encyclopedia of Reagents for Organic Synthesis
(EROS), doi:10.1002/047084289X.rn02570.
Ligand-Enabled Palladium(II)-Catalyzed γ-C(sp
3
)−H Arylation of Primary Aliphatic Amines.
Chen-Hui Yuan
,
Lei Jiao*
January 2024
Org. Lett.
2024
,
26
, 29-34.
Time-Resolved Electron Paramagnetic Resonance Spectrometer Based on Ultrawide Single-Sideband Phase-Sensitive Detection.
Shixue Zhang
,
Shengqi Zhou
,
Jian-Qing Qi
,
Lei Jiao
,
Xingwei Guo*
August 2023
Rev. Sci. Instrum.
2023
,
94
, 084101.
Modular Photoredox System with Extreme Reduction Potentials Based on Pyridine Catalysis.
Lutao Bai
,
Lei Jiao*
July 2023
Chem
2023
,
9
, 3245-3267.
The Stereochemistry of the Reactions between Palladacycle Complexes and Primary Alkyl Iodides.
Xinyu Xu
,
Lei Jiao*
March 2023
Organometallics
2023
,
42
, 606-614.
Ligand-Enabled Pd(II)-Catalyzed Enantioselective β-C(sp
3
)-H Arylation of Aliphatic Tertiary Amides.
Chen-Hui Yuan
,
Xiao-Xia Wang
,
Lei Jiao*
February 2023
Angew. Chem. Int. Ed.
2023
,
62
, e202300854.
Functionalized Cycloolefin Ligand as a Solution to
Ortho
-Constraint in the Catellani-Type Reaction.
Feng-Yuan Wang
,
Yu-Xiu Li
,
Lei Jiao*
February 2023
J. Am. Chem. Soc.
2023
,
145
, 4871-4881.
Asymmetric Defluoroallylation of 4-Trifluoromethylpyridines Enabled by Umpolung C-F Bond Activation.
Fei-Yu Zhou
,
Lei Jiao*
March 2022
Angew. Chem. Int. Ed.
2022
,
61
, e202201102.
Hybrid Cycloolefin Ligands for Palladium/Olefin Cooperative Catalysis.
Ya-Xin Zheng
,
Lei Jiao*
January 2022
Nat. Synth.
2022
,
1
, 180-187.
Divergent Synthesis of Indolenine and Indoline Ring Systems by Palladium-Catalyzed Asymmetric Dearomatization of Indoles.
Dong Gao
,
Lei Jiao*
January 2022
Angew. Chem. Int. Ed.
2022
,
61
, e202116024.
Construction of Indoline/Indolenine Ring Systems by a Palladium-Catalyzed Intramolecular Dearomative Heck Reaction and the Subsequent Aza-Semipinacol Rearrangement.
Dong Gao
,
Lei Jiao*
March 2021
J. Org. Chem.
2021
,
86
, 5727-5743.
Total Synthesis of (-)-Arborisidine.
Feng-Yuan Wang
,
Lei Jiao*
March 2021
Angew. Chem. Int. Ed.
2021
,
60
, 12732-12736.
Recent Developments in Transition-Metal-Free Functionalization and Derivatization Reactions of Pyridines.
Fei-Yu Zhou
,
Lei Jiao*
January 2021
Synlett
2021
,
32
, 159-178.
A Theoretical Study on the Macrocyclic Strain of Zigzag Molecular Belts.
Tan-Hao Shi
,
Shuo Tong
,
Lei Jiao*
,
Mei-Xiang Wang*
November 2020
Organic Materials
2020
,
2
, 300-305.
DFT Study on the Mechanism of 4,4′-Bipyridine-Catalyzed Nitrobenzene Reduction by Diboron(4) Compounds.
Jian-Qing Qi
,
Lei Jiao*
November 2020
J. Org. Chem.
2020
,
85
, 13877-13885.
Regiocontrol in the Oxidative Heck Reaction of Indole by Ligand-Enabled Switch of the Regioselectivity-Determining Step.
Yu-Jie Wang
,
Chen-Hui Yuan
,
De-Zhao Chu
,
Lei Jiao*
October 2020
Chem. Sci.
2020
,
11
, 11042-11054.
Photoinduced Radical Borylation of Alkyl Bromides Catalyzed by 4-Phenylpyridine.
Li Zhang
,
Zhong-Qian Wu
,
Lei Jiao*
January 2020
Angew. Chem. Int. Ed.
2020
,
59
, 2095-2099.
An Umpolung Approach to the Hydroboration of Pyridines: A Novel and Efficient Synthesis of N-H 1,4-Dihydropyridines.
Huan Yang
,
Li Zhang
,
Fei-Yu Zhou
,
Lei Jiao*
January 2020
Chem. Sci.
2020
,
11
, 742-747.
Pd-Catalyzed Carbonylation of Acyl Azides.
Zongyang Li
,
Shiyang Xu
,
Baoliang Huang
,
Chen-Hui Yuan
,
Wenxu Chang
,
Bin Fu
,
Lei Jiao*
,
Peng Wang
,
Zhenhua Zhang*
August 2019
J. Org. Chem.
2019
,
84
, 9497-9508.
Visible-Light-Induced Organocatalytic Borylation of Aryl Chlorides.
Li Zhang
,
Lei Jiao*
June 2019
J. Am. Chem. Soc.
2019
,
141
, 9124-9128.
Cobalt-Catalyzed Regioselective Olefin Isomerization under Kinetic Control.
Xufang Liu
,
Wei Zhang
,
Yujie Wang
,
Ze-Xin Zhang
,
Lei Jiao*
,
Qiang Liu*
June 2018
J. Am. Chem. Soc.
2018
,
140
, 6873-6882.
Aromatization Modulates the Activity of Small Organic Molecules as Promoters for Carbon– Halogen Bond Activation.
Huan Yang
,
De-Zhao Chu
,
Lei Jiao*
February 2018
Chem. Sci.
2018
,
9
, 1534-1539.
Super Electron Donors Derived from Diboron.
Li Zhang
,
Lei Jiao*
January 2018
Chem. Sci.
2018
,
9
, 2711-2722.
Redox-Active Ligand Assisted Multielectron Catalysis: A Case of Co
III
Complex as Water Oxidation Catalyst.
Hao-Yi Du
,
Si-Cong Chen
,
Xiao-Jun Su
,
Lei Jiao*
,
Ming-Tian Zhang*
January 2018
J. Am. Chem. Soc.
2018
,
140
, 1557-1565.
A Convenient Method for the Direct Acquisition of Kinetic Rate Data for Catalytic Organic Reactions by Gas Uptake Measurements.
Yu-Jie Wang
,
Wei-Tang Li
,
Lei Jiao*
January 2018
Asian J. Org. Chem.
2018
,
7
, 570-578.
Asymmetric Total Synthesis of (+)-Minfiensine by an Asymmetric Cascade Cyclization Strategy.
Ze-Xin Zhang
,
Si-Cong Chen
,
Lei Jiao*
October 2017
Synlett
2017
,
28
, 2199-2204.
Pyridine-Catalyzed Radical Borylation of Aryl Halides.
Li Zhang
,
Lei Jiao*
January 2017
J. Am. Chem. Soc.
2017
,
139
, 607-610.
N
-Methylanilines as Simple and Efficient Promoters for Radical-Type Cross-Coupling Reactions of Aryl Iodides.
Huan Yang
,
Li Zhang
,
Lei Jiao*
January 2017
Chem. – Eur. J.
2017
,
23
, 65-69.
The 6th Sino–German Frontiers of Chemistry Symposium (Community Report).
Lei Jiao*
,
Kathrin Lang*
November 2016
Chem. - Asian. J.
2016
,
11
, 3292-3296.
Revisiting the Radical Initiation Mechanism of the Diamine-Promoted Transition-Metal-Free Cross-Coupling Reaction.
Li Zhang
,
Huan Yang
,
Lei Jiao*
June 2016
J. Am. Chem. Soc.
2016
,
138
, 7151-7160.
Total Synthesis of (+)-Minfiensine: Construction of the Tetracyclic Core Structure by an Asymmetric Cascade Cyclization.
Ze-Xin Zhang
,
Si-Cong Chen
,
Lei Jiao*
January 2016
Angew. Chem. Int. Ed.
2016
,
55
, 8090-8094.
Regioselective Direct C-H Alkylation of NH Indoles and Pyrroles by a Palladium/Norbornene-Cocatalyzed Process
Lei Jiao
,
Thorsten Bach*
September 2013
Synthesis
2014
,
46
, 35-41.
Vinylcyclopropane Derivatives in Transition-Metal-Catalyzed Cycloadditions for the Synthesis of Carbocyclic Compounds.
Lei Jiao
,
Zhi-Xiang Yu*
June 2013
J. Org. Chem.
2013
,
78
, 6842-6848.
Palladium-Catalyzed Direct C-H Alkylation of Electron-Deficient Pyrrole Derivatives
Lei Jiao
,
Thorsten Bach*
April 2013
Angew. Chem. Int. Ed.
2013
,
52
, 6080-6083.
Pd(II)-Catalyzed Regioselective 2-Alkylation of Indoles via a Norbornene-Mediated C–H Activation: Mechanism and Applications.
Lei Jiao
,
Eberhardt Herdtweck
,
Thorsten Bach*
August 2012
J. Am. Chem. Soc.
2012
,
134
, 14563-14572.
Palladium-Catalyzed Direct 2-Alkylation of Indoles by Norbornene-Mediated Regioselective Cascade C–H Activation
Lei Jiao
,
Thorsten Bach*
August 2011
J. Am. Chem. Soc.
2011
,
133
, 12990-12993.
Density Functional Theory Study of the Mechanisms and Stereochemistry of the Rh(I)-Catalyzed Intramolecular [3+2] Cycloadditions of 1-Ene- and 1-Yne-Vinylcyclopropanes.
Lei Jiao
,
Mu Lin
,
Zhi-Xiang Yu*
December 2010
J. Am. Chem. Soc.
2011
,
133
, 447-461.
Rh(I)-Catalyzed [(3 + 2) + 1] Cycloaddition of 1-Yne/Ene-vinylcyclopropanes and CO: Homologous Pauson−Khand Reaction and Total Synthesis of (±)-α-Agarofuran.
Lei Jiao
,
Mu Lin
,
Lian-Gang Zhuo
,
Zhi-Xiang Yu*
May 2010
Org. Lett.
2010
,
12
, 2528-2531.
Rh(I)-Catalyzed Intramolecular [3 + 2] Cycloaddition Reactions of 1-Ene-, 1-Yne- and 1-Allene-Vinylcyclopropanes.
Lei Jiao
,
Mu Lin
,
Zhi-Xiang Yu*
December 2009
Chem. Commun.
2010
,
46
, 1059-1061.
New Insights into the Torquoselectivity of the Staudinger Reaction.
Yong Liang
,
Lei Jiao
,
Shiwei Zhang
,
Zhi-Xiang Yu*
,
Jiaxi Xu*
January 2009
J. Am. Chem. Soc.
2009
,
131
, 1542-1549.
Rh(I)-Catalyzed Intramolecular [3 + 2] Cycloaddition of trans-Vinylcyclopropane-enes.
Lei Jiao
,
Siyu Ye
,
Zhi-Xiang Yu*
May 2008
J. Am. Chem. Soc.
2008
,
130
, 7178-7179.
Tandem Rh(I)-Catalyzed [(5+2)+1] Cycloaddition/Aldol Reaction for the Construction of Linear Triquinane Skeleton: Total Syntheses of (±)-Hirsutene and (±)-1-Desoxyhypnophilin.
Lei Jiao
,
Changxia Yuan
,
Zhi-Xiang Yu*
March 2008
J. Am. Chem. Soc.
2008
,
130
, 4421-4430.
Origin of the Relative Stereoselectivity of the β-Lactam Formation in the Staudinger Reaction.
Lei Jiao
,
Yong Liang
,
Jiaxi Xu*
April 2006
J. Am. Chem. Soc.
2006
,
128
, 6060-6069.
A Versatile Method for the Synthesis of 3-Alkoxycarbonyl β-Lactam Derivatives.
Lei Jiao
,
Qianfeng Zhang
,
Yong Liang
,
Shiwei Zhang
,
Jiaxi Xu*
December 2005
J. Org. Chem.
2006
,
71
, 815-818.
Microwave- and Photoirradiation-Induced Staudinger Reactions of Cyclic Imines and Ketenes Generated from α-Diazoketones. A Further Investigation into the Stereochemical Process.
Yong Liang
,
Lei Jiao
,
Shiwei Zhang
,
Jiaxi Xu*
December 2004
J. Org. Chem.
2005
,
70
, 334-337.
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